Tonight’s minor experiment happened just because we had both and it sounded good.
Here’s what ya do:
One shot of UV Cake
One shot of Hi Ho Cherry (with cherry of course)
Take the cake, take the cherry. Win.
Next up. Cherry, then cake. We’ll let you know how that goes, though I’m sure that equals win too. 
Additional: Forgot to add the results of the Cherry Cake. Mainly because it was just that good… So we did a few. 😛 Personally, I thought the Cherry then Cake worked better.